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Title: Laser-Powered Homogeneous Pyrolysis. Thermal Studies under Homogeneous Conditions, Validation of the Technique, and Application to the Mechanism of Azo Compound Decomposition
Journal: J. Phys. Chem.
Volume: 86
Page(s): 709 - 718
Year: 1982
Reference type: Journal article
Squib: 1982MCM/LEW709-718
Reaction:
CH3COOC2H5 → CH3C(O)OH + C2H4
Reaction order:
1
Reference reaction:
CH3COOCH(CH3)2 → CH3C(O)OH + CH3CH=CH2
Temperature:
950 - 1000
K
Pressure: 0.13 bar
Rate expression:
6.31x1012 [s-1] e-205367 [J/mole]/RT
Bath gas:
CO2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 950 | 3.22E1 |
| 975 | 6.28E1 |
| 1000 | 1.18E2 |