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Accessibility information
Author(s):   Pieniazek, M.; Ratajczak, E.
Title:   Kinetics of the abstraction of H from CH3GeCl3, (CH3)4Ge and (C2H5)4Ge by CF3 and C2F5 radicals
Journal:   J. Organometal. Chem.
Volume:   238
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982PIE/RAT289

Reaction:   CH3GeCl3 + C2F5 → Other Products + C2F5H
Reaction order:   2
Reference reaction:   C2F5 + C2F5n-C4F10
Temperature:   351 - 455 K
Pressure:  0.20 bar
Rate expression:   2.96x10-13 [cm3/molecule s] e-29433 [±588 J/mole]/RT
Uncertainty:   1.17
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
351 1.23E-17
375 2.35E-17
400 4.24E-17
425 7.13E-17
450 1.13E-16
455 1.24E-16