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Title: Thermal reaction of hydrogen-butene-2-cis mixtures at 500°C: Hydrogenation, hydrogenolysis, and thermal reaction of the olefin
Journal: Int. J. Chem. Kinet.
Volume: 15
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983COL/RIC5
Reaction:
(Z)-2-C4H8 + sec-C4H9 → n-C4H10 + CH3CH=CCH3
Reaction order:
2
Temperature:
773 - 794
K
Pressure: 1.33E-2 - 0.80 bar
Rate expression:
4.17x10-13 [cm3/molecule s] e-33507 [J/mole]/RT
Bath gas:
H2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 773 | 2.27E-15 |
| 775 | 2.30E-15 |
| 794 | 2.60E-15 |