NIST Chemical Kinetics Database

Author(s):   Jasinski, J.M.; Frisoli, J.K.; Moore, C.B.
Title:   High vibrational overtone photochemistry of cyclobutene
Journal:   J. Chem. Phys.
Volume:   79
Page(s):
Year:   1983
Reference type:   Journal article
Squib:   1983JAS/FRI1312

Reaction:   Cyclobutene → 1,3-Butadiene
Reaction order:   1
Temperature:   410 - 430 K
Pressure:  1.33E-4 - 0.93 bar
Rate expression:   5.75x10¹³ [s^-1] e^{-140515 [J/mole]/RT}
Uncertainty:   2.0
Bath gas:   Cyclobutene
Category: Experiment
Data type:   RRK(M) extrapolation

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
410	7.22E-5
425	3.09E-4
430	4.91E-4