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Author(s):   Kalinenko, R.A.; Buravtseva, E.N.; Nametkin, N.S.; Bach, G.; Zychlinskii, W.; Zimmermann, G.
Title:   Variation of reaction rate constants with hydrocarbon chain length in the pyrolysis of paraffins and α-olefins in different types of reactors
Journal:   Kinet. Catal.
Volume:   24
Page(s):  
Year:   1983
Reference type:   Journal article
Squib:   1983KAL/BUR873

Reaction:   n-C4H10 → Products
Reaction order:   1
Temperature:   973 - 1120 K
Pressure:  1.01 bar
Rate expression:   5.01x1012 [s-1] e-232805 [±11640 J/mole]/RT
Uncertainty:   5.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
973 1.59E0
975 1.69E0
1000 3.46E0
1025 6.86E0
1050 1.31E1
1075 2.44E1
1100 4.42E1
1120 6.96E1