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Accessibility information
Author(s):   Lifshitz, A.; Ben-Hamou, H.
Title:   Thermal reactions of cyclic ethers at high temperatures. 1. Pyrolysis of ethylene oxide behind reflected shocks
Journal:   J. Phys. Chem.
Volume:   87
Page(s):  
Year:   1983
Reference type:   Journal article
Squib:   1983LIF/BEN1782

Reaction:   Oxirane·CH3 + HCO
Reaction order:   1
Temperature:   830 - 1200 K
Pressure:  1.52 - 10.13 bar
Rate expression:   3.63x1013 [s-1] e-239457 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
830 3.09E-2
850 7.00E-2
875 1.84E-1
900 4.60E-1
925 1.09E0
950 2.48E0
975 5.39E0
1000 1.13E1
1025 2.28E1
1050 4.44E1
1075 8.41E1
1100 1.55E2
1125 2.77E2
1150 4.83E2
1175 8.22E2
1200 1.37E3