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Author(s):   Louw, R.; Tinkelenberg, A.; Werner, E.S.E.
Title:   Thermolytic reactions of esters. Part XIII. The effect of electron attracting α-substituents in alkyl acetates
Journal:   Rec. Trav. Chim. Pays/Bas
Volume:   102
Year:   1983
Reference type:   Journal article
Squib:   1983LOU/TIN519

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Temperature:   679 - 737 K
Rate expression:   2.51x1012 [s-1] e-200379 [±2004 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
679 9.66E-4
700 2.80E-3
725 9.19E-3
737 1.58E-2