Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Thermolytic reactions of esters. Part XIII. The effect of electron attracting α-substituents in alkyl acetates
Journal: Rec. Trav. Chim. Pays/Bas
Volume: 102
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983LOU/TIN519
Reaction:
CH3COOC2H5 → CH3C(O)OH + C2H4
Reaction order:
1
Temperature:
679 - 737
K
Rate expression:
2.51x1012 [s-1] e-200379 [±2004 J/mole]/RT
Uncertainty:
2.0
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 679 | 9.66E-4 |
| 700 | 2.80E-3 |
| 725 | 9.19E-3 |
| 737 | 1.58E-2 |