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Title: The mechanism of thermal elimination. Part 17. Rate data for pyrolysis of vinyl acetate and 1,2-diacetoxyethane
Journal: J. Chem. Soc. Faraday Trans. 2
Page(s): 1157 - 1160
Year: 1983
Reference type: Journal article
Squib: 1983TAY1157-1160
Reaction:
CH3C(O)OCH2CH2OC(O)CH3 → CH3C(O)OH + CH3CO2CH=CH2
Reaction order:
1
Temperature:
683 - 691
K
Rate expression:
3.89x1011 [s-1] e-198716 [J/mole]/RT
Bath gas:
CH3C(O)OCH2CH2OC(O)CH3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Nuclear magnetic resonance (NMR)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 683 | 2.47E-4 |
| 691 | 3.70E-4 |