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Title: Quantitative aspects of some unimolecular isomerization rections of organosilicon intermediates
Journal: J. Organometal. Chem.
Volume: 271
Page(s):
Year: 1984
Reference type: Journal article
Squib: 1984DAV/SCA249
Reaction:
Silacyclopent-3-ene,1,1-dimethyl- → 1,3-Butadiene + (CH3)2Si
Reaction order:
1
Temperature:
760 - 850
K
Rate expression:
3.16x1013 [s-1] e-255254 [J/mole]/RT
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 760 | 9.05E-5 |
| 775 | 1.98E-4 |
| 800 | 6.82E-4 |
| 825 | 2.18E-3 |
| 850 | 6.52E-3 |