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Accessibility information
Author(s):   Hidaka, Y.; Chimori, T.; Shiba, S.; Suga, M.
Title:   Decyclization of cyclohexene in shock waves
Journal:   Chem. Phys. Lett.
Volume:   111
Page(s):  
Year:   1984
Reference type:   Journal article
Squib:   1984HID/CHI181

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   1120 - 1330 K
Pressure:  0.13 bar
Rate expression:   1.5x1015 [s-1] e-280198 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1120 1.28E2
1125 1.47E2
1150 2.81E2
1175 5.25E2
1200 9.54E2
1225 1.69E3
1250 2.93E3
1275 4.98E3
1300 8.28E3
1325 1.35E4
1330 1.49E4