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Title: A kinetics investigation of the gas-phase reactions of Cl(2P) and OH(X2II) with CH3CN: Atmospheric significance and evidence for decreased reactivity between strong electrophiles
Journal: J. Phys. Chem.
Volume: 88
Page(s): 3305 - 3308
Year: 1984
Reference type: Journal article
Squib: 1984KUR/KNA3305-3308
Reaction:
CH3CN + Cl → CH2CN + HCl
Reaction order:
2
Temperature:
298
K
Pressure: 2.67E-2 - 6.67E-2 bar
Rate expression:
2.01x10-15 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Resonance fluorescence
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