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Accessibility information
Author(s):   Mackie, J.C.; Doolan, K.R.
Title:   High-temperature kinetics of thermal decomposition of acetic acid and its products
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):  
Year:   1984
Reference type:   Journal article
Squib:   1984MAC/DOO525

Reaction:   CH3C(O)OHCH4 + CO2
Reaction order:   1
Temperature:   1300 - 1950 K
Pressure:  1.01 bar
Rate expression:   5.75x1012 [s-1] e-295164 [J/mole]/RT
Uncertainty:   1.86
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 7.94E0
1350 2.18E1
1400 5.59E1
1450 1.34E2
1500 3.03E2
1550 6.50E2
1600 1.33E3
1650 2.60E3
1700 4.90E3
1750 8.91E3
1800 1.56E4
1850 2.67E4
1900 4.42E4
1950 7.13E4