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Title: Reactions of oxygenated radicals in the gas phase. Part 15. Reactions of t-butylperoxyl radicals with alkenes
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1984
Reference type: Journal article
Squib: 1984MOR/OSB1869
Reaction:
C2H4 + (CH3)3CO2 → Oxirane + (CH3)3CO
Reaction order:
2
Temperature:
393
K
Pressure: 0.27 bar
Rate expression:
5.58x10-21 [cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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