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Title: Reactions of trichloromethyl radicals with organosilicon compounds
Journal: Int. J. Chem. Kinet.
Volume: 16
Page(s): 1505 - 1518
Year: 1984
Reference type: Journal article
Squib: 1984RIC/TRE1505-1518
Reaction:
·CCl3 + SiHCl3 → CHCl3 + SiCl3
Reaction order:
2
Reference reaction:
·CCl3 + ·CCl3 → CCl3CCl3
Temperature:
377 - 498
K
Rate expression:
6.61x10-13 [cm3/molecule s] e-40575 [±2029 J/mole]/RT
Uncertainty:
2.0
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 377 | 1.58E-18 |
| 400 | 3.32E-18 |
| 425 | 6.81E-18 |
| 450 | 1.29E-17 |
| 475 | 2.28E-17 |
| 498 | 3.67E-17 |