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Accessibility information
Author(s):   Rice, J.A.; Treacy, J.J.; Sidebottom, H.W.
Title:   Reactions of trichloromethyl radicals with organosilicon compounds
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   1505 - 1518
Year:   1984
Reference type:   Journal article
Squib:   1984RIC/TRE1505-1518

Reaction:   (CH3)2SiCl2 + ·CCl3CHCl3 + CH3Cl2SiCH2·
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   463 - 588 K
Rate expression:   1.32x10-12 [cm3/molecule s] e-59033 [±2361 J/mole]/RT
Uncertainty:   1.58
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
463 2.89E-19
475 4.25E-19
500 8.98E-19
525 1.77E-18
550 3.26E-18
575 5.72E-18
588 7.52E-18