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Title: Secondary kinetic isotope effects in hydrogen and deuterium abstraction by chlorine atoms from the chloromethyl group in gaseous ethyl chlorides: effects of isotopic substitution in the adjacent methyl group
Journal: J. Photochem.
Volume: 27
Page(s): 141 - 150
Year: 1984
Reference type: Journal article
Squib: 1984TSC/NIE141-150
Reaction:
CD3CH2Cl + Cl → Other Products + HCl
Reaction order:
2
Reference reaction:
CH4 + Cl → ·CH3 + HCl
Temperature:
282 - 368
K
Pressure: 2.67E-2 bar
Rate expression:
2.03x10-11 [±3.99x10-13 cm3/molecule s] e-3193 [±54044 J/mole]/RT
Bath gas:
CD3CH2Cl
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 282 | 5.19E-12 |
| 300 | 5.63E-12 |
| 325 | 6.22E-12 |
| 350 | 6.76E-12 |
| 368 | 7.14E-12 |