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Title: Secondary kinetic isotope effects in hydrogen and deuterium abstraction by chlorine atoms from the chloromethyl group in gaseous ethyl chlorides: effects of isotopic substitution in the adjacent methyl group
Journal: J. Photochem.
Volume: 27
Page(s): 141 - 150
Year: 1984
Reference type: Journal article
Squib: 1984TSC/NIE141-150
Reaction:
CD3CH2Cl + Cl → Other Products + HCl
Reaction order:
2
Reference reaction:
CH4 + Cl → ·CH3 + HCl
Reference reaction order:
2
Temperature:
282 - 368
K
Pressure: 2.67E-2 bar
Rate expression:
1.24±3.7x10-2 e9478 [±95.62 J/mole]/RT
Bath gas:
CD3CH2Cl
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 282 | 7.06E1 |
| 300 | 5.54E1 |
| 325 | 4.14E1 |
| 350 | 3.22E1 |
| 368 | 2.75E1 |