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Title: An evaluation of the kinetic data for the hydrogen transfer reactions: CH3 + CH3COCH3, CD3 + CD3COCD3 and CH3 + CH3NNCH3
Journal: Can. J. Chem.
Volume: 63
Page(s): 3486 - 3491
Year: 1985
Reference type: Journal article
Squib: 1985ART/NEW3486-3491
Reaction:
(CH3)2CO + ·CH3 → CH4 + CH3C(O)CH2(·)
Reaction order:
2
Temperature:
393 - 523
K
Rate expression:
5.76x10-13 [cm3/molecule s] e-40491 [±405 J/mole]/RT
Uncertainty:
1.0700001
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 393 | 2.39E-18 |
| 400 | 2.97E-18 |
| 425 | 6.08E-18 |
| 450 | 1.15E-17 |
| 475 | 2.03E-17 |
| 500 | 3.39E-17 |
| 523 | 5.21E-17 |