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Accessibility information
Author(s):   Brouwer, L.; Muller-Markgraf, W.; Troe, J.
Title:   Identification of primary reaction products in the thermal decomposition of aromatic hydrocarbons
Journal:   Symp. Int. Combust. Proc.
Volume:   20
Page(s):  
Year:   1985
Reference type:   Journal article
Squib:   1985BRO/MUL799

Reaction:   1,4-Dimethylbenzene4-Methylbenzyl +
Reaction order:   1
Temperature:   1400 - 1800 K
Pressure:  0.30 bar
Rate expression:   3.98x1014 [s-1] e-333410 [±16629 J/mole]/RT
Uncertainty:   2.51
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 1.45E2
1425 2.39E2
1450 3.89E2
1475 6.21E2
1500 9.77E2
1525 1.51E3
1550 2.31E3
1575 3.49E3
1600 5.19E3
1625 7.64E3
1650 1.11E4
1675 1.59E4
1700 2.27E4
1725 3.19E4
1750 4.45E4
1775 6.14E4
1800 8.41E4