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Accessibility information
Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   n-C4H10·C2H5 + ·C2H5
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   7.94x1016 [s-1] e-335905 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 2.60E-42
400 1.09E-27
500 6.44E-19
600 4.54E-13
700 6.84E-9
800 9.29E-6
900 2.54E-3
1000 2.26E-1
1100 8.90E0
1200 1.90E2
1300 2.53E3
1400 2.33E4
1500 1.60E5
1600 8.59E5
1700 3.79E6
1800 1.42E7
1900 4.63E7
2000 1.34E8
2100 3.51E8
2200 8.41E8
2300 1.87E9
2400 3.88E9
2500 7.61E9