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Accessibility information
Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   1,3-Butadiene + CH2=CHCH=CH·
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   1.58x1016 [s-1] e-460622 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 9.98E-65
400 1.12E-44
500 1.20E-32
600 1.26E-24
700 6.72E-19
800 1.33E-14
900 2.92E-11
1000 1.38E-8
1100 2.12E-6
1200 1.41E-4
1300 4.91E-3
1400 1.03E-1
1500 1.44E0
1600 1.45E1
1700 1.11E2
1800 6.79E2
1900 3.43E3
2000 1.47E4
2100 5.52E4
2200 1.83E5
2300 5.47E5
2400 1.49E6
2500 3.76E6