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Accessibility information
Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   n-C4H10sec-C4H9 +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   1.0x1016 [s-1] e-397432 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 6.34E-54
400 1.26E-36
500 3.03E-26
600 2.52E-19
700 2.21E-14
800 1.12E-10
900 8.59E-8
1000 1.74E-5
1100 1.34E-3
1200 5.02E-2
1300 1.07E0
1400 1.49E1
1500 1.45E2
1600 1.06E3
1700 6.15E3
1800 2.93E4
1900 1.19E5
2000 4.17E5
2100 1.30E6
2200 3.66E6
2300 9.42E6
2400 2.24E7
2500 4.97E7