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Title: The kinetics and the mechanism of the thermal reaction between sulfurtetrafluoride (SF4) and trifluoromethylhypofluoride (CF3OF)
Journal: Int. J. Chem. Kinet.
Volume: 17
Page(s):
Year: 1985
Reference type: Journal article
Squib: 1985GON/SCH43
Reaction:
CF3OF + SF5 → SF6 + CF3O
Reaction order:
2
Temperature:
415 - 459
K
Pressure: 0.15 - 0.77 bar
Rate expression:
6.44x10-12 [±5.15x10-13 cm3/molecule s] e-40990 [±8314472 J/mole]/RT
Bath gas:
CF3OF
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 415 | 4.47E-17 |
| 425 | 5.91E-17 |
| 450 | 1.12E-16 |
| 459 | 1.39E-16 |