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Accessibility information
Author(s):   Kubat, P.; Pola, J.
Title:   On the characterization of CO2 laser photosensitized reactions
Journal:   Collect. Czech. Chem. Commun.
Volume:   50
Page(s):   1537 - 1542
Year:   1985
Reference type:   Journal article
Squib:   1985KUB/POL1537-1542

Reaction:   CH3CCl3CH2=CCl2 + HCl
Reaction order:   1
Temperature:   1770 - 2900 K
Pressure:  0.36 bar
Rate expression:   2.0x1014 [s-1] e-230311 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1770 3.19E7
1800 4.15E7
1900 9.32E7
2000 1.93E8
2100 3.74E8
2200 6.81E8
2300 1.18E9
2400 1.94E9
2500 3.08E9
2600 4.72E9
2700 7.01E9
2800 1.01E10
2900 1.42E10