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Author(s):   Tschuikow-Roux, E.; Niedzielski, J.; Faraji, F.
Title:   Competitive photochlorination and kinetic isotope effects for hydrogen/deuterium abstraction from the methyl group in C2H6, C2D6, CH3CHCl2, CD3CHCl2, CH3CCl3, and CD3CCl3
Journal:   Can. J. Chem.
Volume:   63
Page(s):   1093 - 1099
Year:   1985
Reference type:   Journal article
Squib:   1985TSC/NIE1093-1099

Reaction:   CH3CCl3 + ClHCl + CCl3CH2
Reaction order:   2
Reference reaction:   CH4 + Cl·CH3 + HCl
Temperature:   280 - 360 K
Pressure:  2.80E-2 bar
Rate expression:   1.68x10-11 [±2.99x10-12 cm3/molecule s] e-17211 [±516 J/mole]/RT
Bath gas:   CH3CCl3
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
280 1.03E-14
300 1.69E-14
325 2.87E-14
350 4.53E-14
360 5.34E-14