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Title: Reactions of ground state chlorine atoms with fluorinated methanes and ethanes
Journal: J. Chem. Phys.
Volume: 82
Page(s): 65 - 74
Year: 1985
Reference type: Journal article
Squib: 1985TSC/YAN65-74
Reaction:
CH3CHF2 + Cl → HCl + CH3CF2
Reaction order:
2
Reference reaction:
C2H5Cl + Cl → HCl + CH2CH2Cl
Temperature:
281 - 368
K
Pressure: 2.67E-2 bar
Rate expression:
1.35x10-11 [±2.66x10-12 cm3/molecule s] e-8481 [J/mole]/RT
Bath gas:
CH3CHF2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 281 | 3.58E-13 |
| 300 | 4.51E-13 |
| 325 | 5.85E-13 |
| 350 | 7.32E-13 |
| 368 | 8.44E-13 |