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Title: Relative rate study of the addition of HO2 radicals of C2H4 and C3H6
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 82
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986BAL/DEA1445
Reaction:
C2H4 + HO2 → Oxirane + ·OH
Reaction order:
2
Reference reaction:
CH3CH=CH2 + HO2 → Methyloxirane + ·OH
Reference reaction order:
2
Temperature:
673 - 773
K
Pressure: 8.00E-2 bar
Rate expression:
2.2±3.1x10-1 e-9312 [±840 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 673 | 4.17E-1 |
| 675 | 4.19E-1 |
| 700 | 4.44E-1 |
| 725 | 4.69E-1 |
| 750 | 4.94E-1 |
| 773 | 5.17E-1 |