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Author(s):   Baldwin, R.R.; Dean, C.E.; Walker, R.W.
Title:   Relative rate study of the addition of HO2 radicals of C2H4 and C3H6
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   82
Year:   1986
Reference type:   Journal article
Squib:   1986BAL/DEA1445

Reaction:   C2H4 + HO2Oxirane + ·OH
Reaction order:   2
Reference reaction:   CH3CH=CH2 + HO2Methyloxirane + ·OH
Reference reaction order:   2
Temperature:   673 - 773 K
Pressure:  8.00E-2 bar
Rate expression:   2.2±3.1x10-1 e-9312 [±840 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
673 4.17E-1
675 4.19E-1
700 4.44E-1
725 4.69E-1
750 4.94E-1
773 5.17E-1