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Accessibility information
Author(s):   Buxton, J.P.; Simpson, C.J.S.M.
Title:   Thermal decarbonylations of unsaturated cyclic ketones: Kinetics and dynamics
Journal:   Chem. Phys.
Volume:   105
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986BUX/SIM307

Reaction:   3-Cyclopenten-1-one1,3-Butadiene + CO
Reaction order:   1
Temperature:   1030 - 1200 K
Pressure:  0.81 bar
Rate expression:   1.58x1012 [s-1] e-168784 [±6760 J/mole]/RT
Uncertainty:   1.58
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1030 4.36E3
1050 6.34E3
1075 9.94E3
1100 1.53E4
1125 2.30E4
1150 3.41E4
1175 4.96E4
1200 7.11E4