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Title: Kinetics of SiF(X2πr) by time-resolved molecular resonance absorption spectroscopy following the reaction of Si(33Pj,31D2,31S0), generated by pulsed irradiation, with fluorinated compounds
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 82
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986HAR/HUS937
Reaction:
CF4 + SiF → ·CF3 + SiF2
Reaction order:
2
Temperature:
300
K
Pressure: 2.67E-2 - 4.00E-2 bar
Rate expression:
3.5x10-11 [±3.82x10-12 cm3/molecule s]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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