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Accessibility information
Author(s):   Mel'nikovich, S.V.; Moin, F.B.
Title:   Kinetics and mechanism of reaction of difluorocarbene with molecular chlorine
Journal:   Kinet. Catal.
Volume:   27
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986MEL/MOI17

Reaction:   ·CF2 + Cl2CF2Cl2
Reaction order:   2
Reference reaction:   ·CF2 + HClCHF2Cl
Temperature:   433 - 523 K
Pressure:  1.01 bar
Rate expression:   5.5x10-16 [cm3/molecule s] e-8813 [±4581 J/mole]/RT
Uncertainty:   2.8199999
Bath gas:   HCl
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
433 4.75E-17
450 5.21E-17
475 5.90E-17
500 6.60E-17
523 7.24E-17