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Title: Kinetics and mechanism of reaction of difluorocarbene with molecular chlorine
Journal: Kinet. Catal.
Volume: 27
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986MEL/MOI17
Reaction:
·CF2 + Cl2 → CF2Cl2
Reaction order:
2
Reference reaction:
·CF2 + HCl → CHF2Cl
Temperature:
433 - 523
K
Pressure: 1.01 bar
Rate expression:
5.5x10-16 [cm3/molecule s] e-8813 [±4581 J/mole]/RT
Uncertainty:
2.8199999
Bath gas:
HCl
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 433 | 4.75E-17 |
| 450 | 5.21E-17 |
| 475 | 5.90E-17 |
| 500 | 6.60E-17 |
| 523 | 7.24E-17 |