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Title: The high temperature pyrolysis of ethylbenzene: Evidence for dissociation to benzyl and methyl radicals
Journal: Int. J. Chem. Kinet.
Volume: 18
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986MIZ/KIE363
Reaction:
Ethylbenzene → Benzyl + ·CH3
Reaction order:
1
Temperature:
1300 - 1800
K
Pressure: 9.33E-2 - 0.73 bar
Rate expression:
3.09x1013 [s-1] e-251097 [J/mole]/RT
Bath gas:
Kr
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Laser schlieren
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1300 | 2.52E3 |
| 1350 | 5.95E3 |
| 1400 | 1.32E4 |
| 1450 | 2.78E4 |
| 1500 | 5.57E4 |
| 1550 | 1.07E5 |
| 1600 | 1.96E5 |
| 1650 | 3.48E5 |
| 1700 | 5.95E5 |
| 1750 | 9.89E5 |
| 1800 | 1.60E6 |