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Accessibility information
Author(s):   Mizerka, L.J.; Kiefer, J.H.
Title:   The high temperature pyrolysis of ethylbenzene: Evidence for dissociation to benzyl and methyl radicals
Journal:   Int. J. Chem. Kinet.
Volume:   18
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986MIZ/KIE363

Reaction:   EthylbenzeneBenzyl + ·CH3
Reaction order:   1
Temperature:   1300 - 1800 K
Pressure:  9.33E-2 - 0.73 bar
Rate expression:   3.09x1013 [s-1] e-251097 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 2.52E3
1350 5.95E3
1400 1.32E4
1450 2.78E4
1500 5.57E4
1550 1.07E5
1600 1.96E5
1650 3.48E5
1700 5.95E5
1750 9.89E5
1800 1.60E6