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Accessibility information
Author(s):   Mizerka, L.J.; Kiefer, J.H.
Title:   The high temperature pyrolysis of ethylbenzene: Evidence for dissociation to benzyl and methyl radicals
Journal:   Int. J. Chem. Kinet.
Volume:   18
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986MIZ/KIE363

Reaction:   EthylbenzeneBenzyl + ·CH3
Reaction order:   1
Temperature:   1300 - 1800 K
Pressure:  9.33E-2 - 0.73 bar
Rate expression:   8.91x1015 [s-1] e-312624 [±9395 J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 2.45E3
1350 7.14E3
1400 1.93E4
1450 4.88E4
1500 1.16E5
1550 2.60E5
1600 5.55E5
1650 1.13E6
1700 2.21E6
1750 4.16E6
1800 7.55E6