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Accessibility information
Author(s):   Robaugh, D.; Tsang, W.
Title:   Mechanism and rate of hydrogen atom attack on toluene at high temperature
Journal:   J. Phys. Chem.
Volume:   90
Page(s):   4159 - 4163
Year:   1986
Reference type:   Journal article
Squib:   1986ROB/TSA4159-4163

Reaction:   Toluene + H2 + Benzyl
Reaction order:   2
Reference reaction:   CH4 + H2 + ·CH3
Temperature:   950 - 1100 K
Pressure:  2.03 - 5.07 bar
Rate expression:   1.99x10-10 [cm3/molecule s] e-34422 [J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
950 2.55E-12
975 2.85E-12
1000 3.17E-12
1025 3.51E-12
1050 3.86E-12
1075 4.24E-12
1100 4.62E-12