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Author(s):   Rogers, D.S.; O'Neal, H.E.; Ring, M.A.
Title:   Comparative trapping kinetics of silylene. 1. Silylene reactions with 1,3-butadiene and acetylene and with 1,3-butadiene and methanol
Journal:   Organometallics
Volume:   5
Page(s):   1467 - 1473
Year:   1986
Reference type:   Journal article
Squib:   1986ROG/ONE1467-1473

Reaction:   1,3-Butadiene + SiH2Silacyclopent-3-ene
Reaction order:   2
Reference reaction:   CH3OH + SiH2CH3OSiH3
Reference reaction order:   2
Temperature:   696 - 1020 K
Pressure:  7.87E-3 - 3.95 bar
Rate expression:   3.69x102 e-24445 [±8314472 J/mole]/RT
Uncertainty:   2.48
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
696 5.40E0
700 5.53E0
725 6.40E0
750 7.32E0
775 8.31E0
800 9.35E0
825 1.05E1
850 1.16E1
875 1.28E1
900 1.41E1
925 1.54E1
950 1.67E1
975 1.81E1
1000 1.95E1
1020 2.07E1