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Author(s):   Rogers, D.S.; O'Neal, H.E.; Ring, M.A.
Title:   Comparative trapping kinetics of silylene. 1. Silylene reactions with 1,3-butadiene and acetylene and with 1,3-butadiene and methanol
Journal:   Organometallics
Volume:   5
Page(s):   1467 - 1473
Year:   1986
Reference type:   Journal article
Squib:   1986ROG/ONE1467-1473

Reaction:   1,3-Butadiene + SiH2Silacyclopent-3-ene
Reaction order:   2
Reference reaction:   C2H2 + SiH2CH≡CSiH3
Reference reaction order:   2
Temperature:   603 - 1030 K
Pressure:  1.00E-2 - 3.67 bar
Rate expression:   4.53 e-2977 [±8314472 J/mole]/RT
Uncertainty:   1.38
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
603 2.50E0
625 2.55E0
650 2.61E0
675 2.67E0
700 2.72E0
725 2.76E0
750 2.81E0
775 2.85E0
800 2.90E0
825 2.94E0
850 2.97E0
875 3.01E0
900 3.04E0
925 3.08E0
950 3.11E0
975 3.14E0
1000 3.17E0
1025 3.19E0
1030 3.20E0