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Accessibility information
Author(s):   Timonen, R.; Kalliorinne, K.; Koskikallio, J.
Title:   Kinetics of reactions of methyl and ethyl radicals with chlorine in the gas phase studied by photochlorination of methane
Journal:   Acta Chem. Scand. Ser. A
Volume:   40
Page(s):   459 - 466
Year:   1986
Reference type:   Journal article
Squib:   1986TIM/KAL459-466

Reaction:   ·CH3 + Br2CH3Br + Br·
Reaction order:   2
Temperature:   298 - 423 K
Pressure:  3.00E-2 - 7.00E-2 bar
Rate expression:   1.93x10-11 [cm3/molecule s] e-299 [J/mole]/RT
Bath gas:   Xe
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.71E-11
300 1.71E-11
325 1.72E-11
350 1.74E-11
375 1.75E-11
400 1.76E-11
423 1.77E-11