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Accessibility information
Author(s):   Tsang, W.
Title:   Single-pulse shock tube study on the stability of perfluorobromomethane
Journal:   J. Phys. Chem.
Volume:   90
Page(s):   414 - 418
Year:   1986
Reference type:   Journal article
Squib:   1986TSA414-418

Reaction:   Cyclohexene, 4-methyl-1,3-Butadiene + CH3CH=CH2
Reaction order:   1
Temperature:   950 - 1100 K
Pressure:  2.53 - 8.11 bar
Rate expression:   2.0x1015 [s-1] e-277703 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
950 1.08E0
975 2.65E0
1000 6.25E0
1025 1.41E1
1050 3.06E1
1075 6.42E1
1100 1.30E2