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Title: Temperature dependence of the rate constants for the addition of OH to benzene and to some monosubstituted aromatics(aniline, bromobenzene, and nitrobenzene) and the unimolecular decay of the adducts. Kinetics into a quasi-equilbrium. 2
Journal: J. Phys. Chem.
Volume: 90
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986WIT/URB3251
Reaction:
aniline + ·OH → Products
Reaction order:
2
Temperature:
239 - 358
K
Pressure: 0.13 bar
Rate expression:
1.69x10-11 [cm3/molecule s] e4656 [±233 J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Resonance fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 239 | 1.76E-10 |
| 250 | 1.59E-10 |
| 275 | 1.30E-10 |
| 300 | 1.10E-10 |
| 325 | 9.49E-11 |
| 350 | 8.39E-11 |
| 358 | 8.09E-11 |