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Author(s):   Batt, L.; Robinson, G.N.
Title:   Decomposition of the t-Butoxy radical. I. Studies over the temperature range 402-443 K
Journal:   Int. J. Chem. Kinet.
Volume:   19
Year:   1987
Reference type:   Journal article
Squib:   1987BAT/ROB391

Reaction:   (CH3)3CO· → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   402 - 443 K
Pressure:  4.00E-2 - 1.33 bar
Rate expression:   3.98x1014 [s-1] e-66931 [±5355 J/mole]/RT
Uncertainty:   5.0
Bath gas:   CF4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
402 8.00E5
425 2.37E6
443 5.11E6