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Accessibility information
Author(s):   Cohen, N.; Benson, S.W.
Title:   Empirical correlations for rate coefficients for reactions of OH with haloalkanes
Journal:   J. Phys. Chem.
Volume:   91
Page(s):   171 - 175
Year:   1987
Reference type:   Journal article
Squib:   1987COH/BEN171-175

Reaction:   CHCl3 + ·OH → ·CCl3 + H2O
Reaction order:   2
Temperature:   290 - 306 K
Rate expression:   1.22x10-12 [cm3/molecule s] e-4656 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
290 1.77E-13
300 1.89E-13
306 1.96E-13