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Accessibility information
Author(s):   Kiefer, J.H.; Shah, J.N.
Title:   Unimolecular dissociation of cyclohexene at extremely high temperatures: Behavior of the energy-transfer collision efficiency
Journal:   J. Phys. Chem.
Volume:   91
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987KIE/SHA3024

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   1200 - 1800 K
Pressure:  0.20 - 0.47 bar
Rate expression:   3.72x1015 [s-1] e-275209 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 3.90E3
1250 1.18E4
1300 3.26E4
1350 8.36E4
1400 2.01E5
1450 4.54E5
1500 9.71E5
1550 1.98E6
1600 3.86E6
1650 7.22E6
1700 1.30E7
1750 2.27E7
1800 3.84E7