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Title: Unimolecular dissociation of cyclohexene at extremely high temperatures: Behavior of the energy-transfer collision efficiency
Journal: J. Phys. Chem.
Volume: 91
Page(s):
Year: 1987
Reference type: Journal article
Squib: 1987KIE/SHA3024
Reaction:
Cyclohexene → C2H4 + 1,3-Butadiene
Reaction order:
1
Temperature:
1200 - 1800
K
Pressure: 0.20 - 0.47 bar
Rate expression:
3.72x1015 [s-1] e-275209 [J/mole]/RT
Bath gas:
Kr
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1200 | 3.90E3 |
| 1250 | 1.18E4 |
| 1300 | 3.26E4 |
| 1350 | 8.36E4 |
| 1400 | 2.01E5 |
| 1450 | 4.54E5 |
| 1500 | 9.71E5 |
| 1550 | 1.98E6 |
| 1600 | 3.86E6 |
| 1650 | 7.22E6 |
| 1700 | 1.30E7 |
| 1750 | 2.27E7 |
| 1800 | 3.84E7 |