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Accessibility information
Author(s):   Kiefer, J.H.; Shah, J.N.
Title:   Unimolecular dissociation of cyclohexene at extremely high temperatures: Behavior of the energy-transfer collision efficiency
Journal:   J. Phys. Chem.
Volume:   91
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987KIE/SHA3024

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   1200 - 2000 K
Pressure:  0.14 - 0.23 bar
Rate expression:   4.6x1039 [s-1] (T/298 K)-25.30 e-483071 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 2.14E3
1250 5.28E3
1300 1.17E4
1350 2.36E4
1400 4.37E4
1450 7.52E4
1500 1.21E5
1550 1.85E5
1600 2.67E5
1650 3.68E5
1700 4.87E5
1750 6.21E5
1800 7.66E5
1850 9.16E5
1900 1.07E6
1950 1.21E6
2000 1.34E6