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Accessibility information
Author(s):   Kiefer, J.H.; Shah, J.N.
Title:   Unimolecular dissociation of cyclohexene at extremely high temperatures: Behavior of the energy-transfer collision efficiency
Journal:   J. Phys. Chem.
Volume:   91
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987KIE/SHA3024

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   1200 - 2000 K
Pressure:  0.48 - 0.73 bar
Rate expression:   9.51x1037 [s-1] (T/298 K)-23.60 e-465610 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 2.72E3
1250 6.70E3
1300 1.49E4
1350 3.01E4
1400 5.61E4
1450 9.74E4
1500 1.59E5
1550 2.44E5
1600 3.57E5
1650 4.98E5
1700 6.68E5
1750 8.64E5
1800 1.08E6
1850 1.31E6
1900 1.55E6
1950 1.79E6
2000 2.02E6