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Accessibility information
Author(s):   Lifshitz, A.; Moran, A.; Bidani, S.
Title:   Thermal reactions of acetonitrile at high temperatures. Pyrolysis behind reflected shocks
Journal:   Int. J. Chem. Kinet.
Volume:   19
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987LIF/MOR61

Reaction:   CH3CNCH2CN +
Reaction order:   1
Temperature:   1350 - 1950 K
Pressure:  4.05 bar
Rate expression:   6.17x1015 [s-1] e-404083 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1350 1.43E0
1400 5.18E0
1450 1.71E1
1500 5.24E1
1550 1.49E2
1600 3.97E2
1650 9.96E2
1700 2.37E3
1750 5.36E3
1800 1.16E4
1850 2.41E4
1900 4.80E4
1950 9.25E4