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Accessibility information
Author(s):   Pamidimukkala, K.M.; Kern, R.D.; Patel, M.R.; Wei, H.C.; Kiefer, J.H.
Title:   High-temperature pyrolysis of toluene
Journal:   J. Phys. Chem.
Volume:   91
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987PAM/KER2148

Reaction:   Toluene·CH3 + Phenyl
Reaction order:   1
Temperature:   1600 - 2100 K
Pressure:  0.51 bar
Rate expression:   8.91x1012 [s-1] e-303478 [J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1600 1.10E3
1650 2.20E3
1700 4.22E3
1750 7.79E3
1800 1.39E4
1850 2.41E4
1900 4.04E4
1950 6.62E4
2000 1.06E5
2050 1.65E5
2100 2.52E5