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Accessibility information
Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part 2. Methanol
Journal:   J. Phys. Chem. Ref. Data
Volume:   16
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987TSA471

Reaction:   CH3OH·CH3 + ·OH
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   1.9x1016 [s-1] e-384129 [J/mole]/RT
Uncertainty:   2.0
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 2.50E-51
400 1.31E-34
500 1.41E-24
600 6.89E-18
700 4.12E-13
800 1.58E-9
900 9.66E-7
1000 1.64E-4
1100 1.09E-2
1200 3.62E-1
1300 6.99E0
1400 8.85E1
1500 7.99E2
1600 5.48E3
1700 2.99E4
1800 1.35E5
1900 5.23E5
2000 1.76E6
2100 5.30E6
2200 1.44E7
2300 3.59E7
2400 8.29E7
2500 1.79E8