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Title: Kinetics and mechanism of the thermal reactions of endo- and exo-5-cyanobicyclo[2.2.2]oct-2-ene and methyl-substituted derivatives in the gas phase
Journal: Int. J. Chem. Kinet.
Volume: 19
Page(s):
Year: 1987
Reference type: Journal article
Squib: 1987VAN/HUY885
Reaction:
Bicyclo[2.2.2]oct-5-ene-2-carbonitrile,(1α,2α,4α)- → CH2CHCN + 1,3-Cyclohexadiene
Reaction order:
1
Temperature:
518 - 605
K
Pressure: 1.07E-2 - 3.33E-2 bar
Rate expression:
6.76x1014 [s-1] e-226985 [J/mole]/RT
Uncertainty:
1.05
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 518 | 8.74E-9 |
| 525 | 1.76E-8 |
| 550 | 1.88E-7 |
| 575 | 1.62E-6 |
| 600 | 1.17E-5 |
| 605 | 1.71E-5 |