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Accessibility information
Author(s):   Wallington, T.J.; Kurylo, M.J.
Title:   The gas phase reactions of hydroxyl radicals with a series of aliphatic alcohols over the temperature range 240-440 K
Journal:   Int. J. Chem. Kinet.
Volume:   19
Year:   1987
Reference type:   Journal article
Squib:   1987WAL/KUR1015

Reaction:   C2H5OH + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   240 - 440 K
Pressure:  3.33E-2 - 6.67E-2 bar
Rate expression:   7.41x10-12 [±3.16x10-12 cm3/molecule s] e-1995 [±915 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
240 2.72E-12
250 2.84E-12
275 3.09E-12
300 3.33E-12
325 3.54E-12
350 3.73E-12
375 3.91E-12
400 4.06E-12
425 4.21E-12
440 4.29E-12