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Author(s):   Baggott, J.E.; Blitz, M.A.; Frey, H.M.; Lightfoot, P.D.; Walsh, R.
Title:   Absolute rate measurements for some gas-phase addition reactions of dimethylsilylene
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   84
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988BAG/BLI515

Reaction:   1,3-Butadiene + (CH3)2Si → Adduct
Reaction order:   2
Temperature:   298 K
Pressure:  6.67E-3 bar
Rate expression:   7.46x10-11 [±4.48x10-12 cm3/molecule s]
Bath gas:   SF6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

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