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Title: Absolute rate measurements for some gas-phase addition reactions of dimethylsilylene
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 84
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988BAG/BLI515
Reaction:
1,3-Butadiene + (CH3)2Si → Adduct
Reaction order:
2
Temperature:
298
K
Pressure: 6.67E-3 bar
Rate expression:
7.46x10-11 [±4.48x10-12 cm3/molecule s]
Bath gas:
SF6
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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