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Accessibility information
Author(s):   Brouwer, L.D.; Muller-Markgraf, W.; Troe, J.
Title:   Thermal decomposition of toluene: A comparison of thermal and laser-phochemical activation experiments
Journal:   J. Phys. Chem.
Volume:   92
Page(s):   4905 - 4914
Year:   1988
Reference type:   Journal article
Squib:   1988BRO/MUL4905-4914

Reaction:   TolueneBenzyl +
Reaction order:   1
Temperature:   1450 - 1900 K
Pressure:  6.44 bar
Rate expression:   2.82x1015 [s-1] e-371657 [±11141 J/mole]/RT
Uncertainty:   1.58
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1450 1.15E2
1475 1.94E2
1500 3.22E2
1525 5.25E2
1550 8.43E2
1575 1.33E3
1600 2.08E3
1625 3.19E3
1650 4.84E3
1675 7.25E3
1700 1.07E4
1725 1.57E4
1750 2.28E4
1775 3.26E4
1800 4.63E4
1825 6.50E4
1850 9.05E4
1875 1.25E5
1900 1.71E5